Molecular diffusion in ternary poly(vinyl alcohol) solutions
نویسندگان
چکیده
Abstract The diffusion kinetics of a molecular probe—rhodamine B—in ternary aqueous solutions containing poly(vinyl alcohol), glycerol, and surfactants was investigated using fluorescence correlation spectroscopy dynamic light scattering. We show that the characteristics rhodamine B in such complex systems is determined by synergistic effect crowding intermolecular interactions between chemical species. presence glycerol has no noticeable impact on at low concentration, but significantly slows down above 3.9% (w/v) due to dominating steric inhibition effect. Furthermore, introducing (cationic/nonionic/anionic) system results decreased coefficient probe. In nonionic surfactant, this can be explained an increased For alcohol) cationic or anionic surfactant—polymer surfactant—rhodamine alongside molecules slow overall diffusivity B. advance our insight migration broad range industrial formulations incorporate multiple compounds, highlight importance selecting appropriate additives formulated products.
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ژورنال
عنوان ژورنال: Frontiers of Chemical Science and Engineering
سال: 2021
ISSN: ['2095-0187', '2095-0179']
DOI: https://doi.org/10.1007/s11705-021-2121-3